Spectroscopic determination of relative Brønsted acidity as a predictor of reactivity in aprotic ionic liquids.

نویسندگان

  • Ariel I Horowitz
  • Paola Arias
  • Matthew J Panzer
چکیده

A simple titration technique utilizing pyridine as a FTIR spectroscopy probe is demonstrated to successfully predict relative Brønsted acid-limited reaction rates in different ionic liquid (IL) environments. Relative acidity is shown to vary across three aprotic ILs in a manner that is specific to the particular acid-IL pairing.

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عنوان ژورنال:
  • Chemical communications

دوره 51 30  شماره 

صفحات  -

تاریخ انتشار 2015